Fashion compatibility modeling methods work towards automatically accessing the matching degree among a set of complementary items by exploring the multi-modal contents of items, like images and textual descriptions. They, however, overlook the user subjective factors. Inspired by this, a few pioneers study the Personalized Fashion Compatibility Modeling (PFCM) by concentrating on the user and item entities, as well as their interactions. Despite their significance, the existing PFCM methods ignore the attribute entities, which contain rich semantics. To address this problem, we propose to fully explore the related entities and their relations involved in PFCM to boost the PFCM performance. This is, however, non-trivial due to the heterogeneous contents of different entities, embeddings for new users, and various high-order relations. Towards these end, we present a novel metapath-guided personalized fashion compatibility modeling, dubbed as MG-PFCM. In particular, we creatively build a heterogeneous graph to unify the three types of entities (i.e., users, items, and attributes) and their relations (i.e., user-item interactions, item-item matching relations, and item-attribute association relations). Thereafter, we design a multi-modal content-oriented user embedding module to learn user representations by inheriting the contents of their interacted items. Meanwhile, we define the user-oriented and item-oriented metapaths, and perform the metapath-guided heterogeneous graph learning to enhance the user and item embeddings. In addition, we introduce the contrastive regularization to improve the model performance. We conduct extensive experiments on the real-world benchmark dataset, which verifies the superiority of our proposed scheme over several cutting-edge baselines.